Spectacular Spiderman: The Complete Series These adventures find our hero tackling more Super Villains both old and new, including Chameleon, Venom and the Sinister Six: Electro, Doctor Octopus, Vulture, Sandman, Rhino and Shocker. While these criminals are almost more than Spidey can handle, his real struggle becomes an internal one. The stress is enough to drive a high school Super Hero over the edge, but making mistakes and learning lessons is all in a days work for the Spectacular Spider-Man (TM).